You need to add the machine to AD domain first.
s1. Log in with an Active Directory user account
s2. Start Firefox and come to about:config page
s3. Add domainl of authenicating website that using NTLM to the Value network.automatic-ntlm-auth.trusted-uris
s4. Go to url of authenticating website that uses NTLM
for setting linux client refer to:
for windows server settings refer to:
VP4. Should be able to access web page without entering credentials